International Journal of Materials Engineering and Technology
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Abstract: Three
sorel
cement mixes were prepared from different molecular proportions of MgOand
pure
chemicals using the optimum amount of water. The prepared mixes were referred to
as mixes nos. 1, 2 and 3 corresponding to 2.8 : 1.2, 3 : 1 and 3.2 : 0.8 of MgO
and respectively.
Different
instrumental analyses were used to investigate the solid phases constituted by
the hydrated cement mixes, these are; X-ray diffraction (XRD), thermal analysis
including thermogravimetry (TG)and
differential thermal analysis (DTA), Infrared transmittance (IR) as well asscanning electron microscope (SEM) attached with energy dispersive X-ray
unit (EDX). Characterization of the prepared cements were carried out through
determination of the physicomechanical properties involving heat of hydration
and sintering parameters (bulk density and apparent porosity) and cementing
properties involving water of consistency (WOC), initial and final setting times
(ST), as well as mechanical strength (cold crushing strength) as a function of
the age of hydration.
It is concluded that
the optimum molecular proportion for preparing
sorel
cement is 3 : 1 MgO and respectively. It consumes a moderate
amount of mixing water and characterized with short setting time, high heat of
hydration, good sintering parameters as well as high cold crushing strength
values at different ages of hydration compared with the other cement
mixes. The improved properties are due to the fact that this mix composition was
suitable to form stable
sorel
cement, F3 form which is responsible for hydration
and hardening discussed.
Keywords and phrases: sorel cement, magnesia, physicomechanical properties.